Thursday, October 31, 2019

Service visit and analyzes assignment 1 Essay Example | Topics and Well Written Essays - 1000 words

Service visit and analyzes assignment 1 - Essay Example It can be stated that this service provider though operates in a small space with limited guest arrangements but provides high quality food items to its customers. The restaurant even maintains customer relationship through taking details of their guests and informing them about discounts or new dishes being introduced in their menu list. On the other hand Club A Steakhouse is a restaurant that serves high-end customers and is the most famous steakhouse in the city. This restaurant has differentiated its service through creating an artistic ambience, proper lighting, soothing music and excellent food (Bryson and Daniels 112). Club A Steakhouse was established in the year 2008 and since then it has been able to maintain family hospitality in its service with wide range of choices in terms of menu items. Little Owl restaurant believes that it can maintain its market share through delivering high quality food and develops an atmosphere of casual dining. However I feel that ambience is necessary for any restaurant apart from offering good food. As customers spend their valuable time in food outlets so it becomes essential to create an atmosphere that enhances their experience. The seating arrangement of this restaurant is not appropriate which creates a bad impression on customer mindset. On the contrary, Club A Steakhouse is the perfect destination for all those customers who are looking for proper dining with classic ambience. It has drawn a positive impression about the restaurant and I feel that its sophisticated culture is suitable enough for customers to spend their personal time. The restaurant even gives special attention to each of the customers and organizes private events to promote their service quality. In Little Owl restaurant aroma and structural shape are some of the physical evidences that have influenced my customer experience. This restaurant

Tuesday, October 29, 2019

Banquos Murder Macbeth Essay Example for Free

Banquos Murder Macbeth Essay This morning, our beloved Banquo, friend of the king, was found dead. His body, bearing a slit throat and twenty deep lacerations to the face, was discovered by a farmer from the area. The farmer discovered the body outside of his Salmon farm roughly a mile from castle Dunsinane. The motive for this horrific act is still questionable. Upon questioning the farmer police were unable to discover any leads. Although the farmer produced no useful information the crime scene yielded a possible location for authorities to begin the search. When officials investigated the ditch were Banquo was found they observed footprints and drags marks that led to the road outside Castle Dunsinane, there was also another set of footprints that led straight to the castle to suggest a possible connection between the castle and the murderers. When the authorities found the scene where Banquo was expected to be murdered, a total of five sets of footprints were found at the crime scene along with blood and two sets of horse’s hoofs. The police were able to eliminate two sets of footprints as Banquo’s and another as his son Fleance’s, based on the size. What still concerns authorities is the disappearance of the young Fleance. The boy was thought to be with Banquo at the time of the murder. Police are searching for the boy diligently. The face of the murdered Banquo after his body was found a mile from Castle Dunsinane. The face of the murdered Banquo after his body was found a mile from Castle Dunsinane. From the crime scene the police have concluded that they are looking for three possible murders. With the fifth set of footprints leading away from the scene, police began their search at the castle. The authorities talked with King Macbeth, who was reported to have been acting strangely at the court gathering the previous night. The king said, â€Å"I drink to†¦our dear friend Banquo, whom we miss. † The king continued on to say that he will miss his good friend and also hopes that Banquo finds heaven. Lady Macbeth was also asked for a statement and she refused, saying only she was too weak with sadness to speak of the event. In conclusion, authorities have no credible leads or motives for this terrible crime at this time. Police ask that anyone with any information regarding the murderers contact them at their field office. Their office is in Castle Dunsinane on the second floor, they ask that people with information please contact them as soon as possible.

Saturday, October 26, 2019

The Importance Of Heat Integration In Distillation Columns Engineering Essay

The Importance Of Heat Integration In Distillation Columns Engineering Essay The combination of high crude oil prices due to increasing energy demand and concern about pollution has led researchers to exploring the possibilities of more energy efficient and environmentally friendly process technologies. The importance of distillation as a separation technique has made making it more energy efficient a high priority. Consequently, many heat integrated design schemes have been produced through the decades that it has been investigated and many of these techniques are outlined in this report along with some current commercial schemes. However, this technology has not been fully commercialised and this is mainly due to the high initial investment costs and the complexities of the equipment design, control schemes and operation. There is also a lack of real experimental data that is needed in order to verify the many theoretical predictions that claim that large energy saving are possible. Several areas have been identified as in need of further research in the fu ture to hopefully allow this technology to become an industrial standard and not just a theory. Introduction 1.1 The Importance of Heat Integration in Distillation Columns The combined threat of increasing energy demands and costs, global warming and the increased dependence upon oil imported from politically unstable parts of the world have resulted in an interest in enhancing the thermodynamic efficiency of current industrial processes. Increasing energy efficiency in chemical processes not only provides economic benefits but also it leads to reduce the emissions resulting from the process operation. Distillation is perhaps the most important and widely used separation technique in the world today as it is used for about 95% of all fluid separation in the chemical industry. In the US, about 10% of the industrial energy consumption accounts for distillation while it accounts for an estimated 3% of the world energy consumption. More than 70% of the operation costs are caused by the energy expenses (Nakaiwa et al. 2003.) It is a fact that the energy consumption in distillation and CO2  gases produced in the atmosphere are strongly related as the highe r the energy demands are the larger the CO2  emissions to the atmosphere are. This is due to the energy being mostly generated through the combustion of fossil fuel. Despite its apparent importance the overall thermodynamic efficiency of a conventional distillation is only around 5-20% (Jana, 2009). Clearly, improving on this value is imperative and a top priority objective. In order to achieve this, the concept of heat integration was introduced almost 70  years ago (Jana, 2009.) The basic idea of heat integration is that the hot process streams are heat exchanged with cold process streams which results in a more economic use of resources. Consequently a whole range of heat integrated distillation schemes have been proposed. In a conventional distillation column (Figure  1) with a feed, a top product and a bottom product, heat is added at the bottom of the stripping section. In distillation, heat is used as the separating agent. The heat is conventionally supplied at the bottom reboiler in order to evaporate a liquid mixture but is lost when liquefying the overhead vapour at the reflux condenser. The temperature of this heat corresponds to the highest temperature point in the distillation column. The temperature of the heat rejected at the top of the rectifying section corresponds to the lowest temperature point in the distillation column. Thus, distillation involves the loss of heat from a higher temperature level to a lower temperature level in order to perform the work of separation. The efficiency of distillation is reduced if the heat rejected in the rectifying section of the distillation column is not reutilized (Smith, 2005.) This is the principle from which heat integration of distillation is m ainly based. Full-size image (28 K) Figure A schematic representation of a conventional distillation column (Kiran, 2012) 1.2 Benefits and Drawbacks of Heat Integration The possible benefits of heat integration tend to be potential energy savings due to greater efficiency and also less waste. Unfortunately due to a number of issues the technology has yet to be commercialised. Installation of any type of heat integration will entail a higher capital investment than that of any standard distillation column due to the increased complexity of the design. Also, the amount by which the efficiency is improved by is not always substantial in certain cases and therefore it must be considered whether the perceived benefits from the greater efficiency outweigh those of the added costs. The increased complexity can also increase the difficulty of designing, operating and controlling the system. There has also been a lack of experimental data for large scale examples to verify theoretical predictions. A successful heat integrated column design would show positive energy savings at reasonable economic figures that can be effectively operated and controlled. 2. Energy-efficient distillation techniques This section discusses some of the many heat integrated techniques that have so far been proposed with the purpose of improving the energy efficiency of separation processes. 2.1 Pseudo-Petlyuk column The thermally coupled distillation scheme was first patented by Brugma in 1937. The process is used for separating a ternary feed and consists of a conventional prefractionator and side stream tower. Both of these parts are equipped with a reboiler and a condenser. The unit is divided vertically by a wall through a set of trays in order to keep the feed stream and side product separated. It was Wolff and Skogestad (1995)who referred to this set up as a pseudo-petluk column. However, their research led to some concerns about serious issues during operation for high purity separations which would limit the effective use of this system in many cases (Wolff, 1995.) 2.2 The Divided-Wall Column The elimination of the prefractionator unit from the pseudo-Petlyk column leads to a configuration known as the divided-wall column (DWC) (Robin Smith et al, 1992.) It is displayed in figure 2. It is achieved by introducing a vertical partition into a distillation column to arrange a prefractionator and a main column inside a single shell. The advantage of this partitioned column is that a ternary mixture can be distilled into pure product streams with only one distillation structure, one condenser and one reboiler. Naturally the cost of the separation is reduced along with the number of equipment units which leads to a reduced initial investment cost. Subsequently, further research has been undertaken with for example Agrawal (2001) discussing for multicomponent mixture separation the various types of partitioned columns and their advantages and disadvantages. However, as a result of the lack of experience in design and control, the dividing wall columns were yet to be extensively used in industry. This is changing though and there has been a rapid growth in the number of units in use. In 2004 there were 40 units used worldwide (Adrian et al, 2004) Full-size image (11 K) Figure A schematic representation of a Petlyuk distillation column (also known as divided-wall column) (Jana, 2009). 2.3. Petlyuk column Petlyuk et al (1965) presented a detailed theoretical study on a divided-wall column called the Petlyuk column. This reduced Petlyuk structure involves low initial investment and consumes less energy which reduces the operating costs. However, upon comparison with a conventional distillation unit the Petlyuk column has many more degrees of freedom in both design and operation which can cause difficulty when designing the column and creating a control system. As displayed in figure 3, the two-column Petlyk configuration will commonly consist of a prefractionator connected to a distillation shell equipped with only one condenser and reboiler (Jana, 2009.). The thermal coupling in a Petyluk scheme has lead to large energy savings. Unfortunately, little progress has been made with regard to improving operation and control of the structure which hinders its usability. . Full-size image (20 K) Figure A schematic representation of a two-column Petlyuk structure. (Jana,2009) 2.4 Multi-Effect Column The basic idea of this method for separating multicomponent mixtures is to use the overhead vapour of the one column as the heat source in the reboiler for the next column. The columns may be heat integrated in the direction of the mass flow which is forward integration or back integration can be used with is in the opposite direction. A sample column that represents a multi-effect column with a prefractionator for a ternary mixture separation is displayed in figure 4. Full-size image (19 K) Figure A schematic representation of a multi-effect system for ternary (A-C) feed mixture (Jana, 2009) This integrated arrangement has been proved to provide considerable energy savings (Cheng et al, 1985.) However, the issue preventing commercialisation of the process is the operation difficulties owed to the nonlinear, multivariable and interactive nature of the process (Han et al, 1996.) More research must be undertaken to try and find appropriate solutions before there can be a more extensive use for this system and to make use of the energy saving potential. 2.5 Heat Pump-assisted Distillation Column The heat pump is mainly used as a way for increasing the thermal economy of a single distillation column. The heat pump-assisted distillation column or vapour recompression column (VRC) was implemented as an energy-efficient process for the chemical industries after an oil crisis in 1973 (Jana, 2009.) In the system the overhead vapour is pressurised by a compressor to the point where it can be condensed at an increased temperature which will supply the heat required in the reboiler. A schematic representation of this can be seen in figure 5. Full-size image (14 K) Figure A schematic representation of a heat pump-assisted distillation column (Jana, 2009) There are potentially large energy savings to be made, mainly for fractionating close boiling mixtures. This is due to the small temperature difference between the top and bottom of the column which will result in small compression ratios and consequently small compressor duties being required (De Rijke, 2007.) For a conventional distillation column attempting to fractionate the same close boiling mixture there will be a higher reflux ratio and thus larger reboiler duties would be required. The drawback for this technique is the high capital costs. Reducing the cost of running the heat pump-assisted distillation column would certainly increase its cost effectiveness and make it more viable as an option. 2.6 Heat integrated distillation column Using heat pump technology it is possible for separate rectifying columns and stripping columns to be heat integrated internally. This structure is a heat integrated distillation column (HIDiC.) Originally only part of the stripping and rectifying sections were integrated under the name of the SRV scheme but later column design has incorporated heat integration between the whole rectifying and stripping sections (Jana, 2009.) Figure 6 displays a typical partial energy integrated distillation scheme. Full-size image (26 K) Figure A schematic representation of a partial HIDiC scheme (Jana, 2009)) In this configuration the stripping column operates at pressure lower than the rectifying column. A compressor and throttling valve are installed in order to adjust the pressures. The pressure differential means there will be a corresponding difference in operating temperature which allows energy to be transferred between the two columns through heat exchangers. Reflux flow for the rectifying section and vapour flow for the stripping section is generated from the heat exchanged between the rectifying hot vapour and the stripping cold liquids. This allows the reboiler heat load to be substantially reduced. Less energy is consumed the more heat that is exchanged and through appropriate process design it can be possible for reflux and/or reboil free operations to be performed. It has been shown that the HIDiC, compared to the VRC, can lead to energy savings of about 50% (Sun et al, 2003.) However, the structure has a very complex design and requires large capital investment (Jana, 2009.) Meanwhile it has also been found find that there are many binary feed separations where HIDiC is actually less energy efficient than simple heat pump schemes using only one or two heat transfer locations. Furthermore, it was shown that the energy efficiency of HIDiC cannot be solely decided based on the feed composition or product purities as many calculations are based. A better performance indicator is the temperature profile along the height of the rectifying section relative to the corresponding temperature profile in the stripping section (Herron ,2011) Research is ongoing, focussing on the dynamics and the thermodynamic efficiency aspects while extensive research was undertaken by Suphanit (2011) focussing on optimal heat distribution depending on the column arrangement and number of heat exchangers. Suphanit also produced a couple of potential schemes display in figure 7. Full-size image (41 K) Figure Fig. 2. Internally heat-integrated distillation column (HIDiC) (a) and HIDiC constructed in a concentric column (b) (Suphanit, 2011) The development of HIDiC has now reached the pilot plant stage in some countries such as Japan and the Netherlands.  Despite this, further research, both in terms of design and hardware development issues, is still needed before this application can be fully established and accepted in commercial use while further detailed study on the economic evaluation of this column structure is needed in order to ensure its advantage over more conventional schemes (Suphanit, 2011.) 2.7 Heat Integrated Batch Distillation Column Batch distillation is generally known to be a less energy efficient option than its continuous counterpart. However, the batch distillation is extensively used in pharmaceutical, fine and specialty chemicals industry due to its greater flexibility where the demand and lifetime of the products can be uncertain and may vary significantly with time. Jana (2009) proposed a novel heat integrated batch distillation column (HIBDC.) The proposal was based on a binary batch distillation example that separates an equimolar ethanol/water mixture. In comparison with the conventional batch process, the HIBDC also includes a compressor. The produced vapour in this concentric reboiler is firstly compressed and is then introduced at the bottom of the rectifier. This results in a pressure difference between the rectifier and reboiler. Consequently, energy is exchanged from the rectifier to the reboiler through the internal wall and brings the downward liquid flow for the former and upward vapour flow for the latter. This reduces the reboiler and condenser heat loads. However, an additional compressor duty is involved in the thermally coupled column. Full-size image (28 K) Figure Schematic of a heat integrated batch distillation column (HIBDC) [D = distillate rate (kmol/h), L1 = flow rate of liquid leaving 1st tray (kmol/h), nt = top tray, Qc = condenser duty (kW), Qn = rate of internal heat transfer from nth tray (kW),R = ref reflux rate (kmol/h),  VB  =  vapor boil-up rate (kmol/h)] (Jana, 2009) From the investigation it was observed that the HIBDC system appears overwhelmingly superior to its conventional stand alone column providing a significant savings in energy as well as cost. The potential energy integration leads to achieving about 56.10% energy savings and 40.53% savings in total annual cost. However, a single example comparing different configurations does not indicate that the proposed method would perform equally successfully for all mixtures. Therefore it was proposed that further investigation would take place in the future to come to a full conclusion as to the future promise of this technique. Takamatsu et al. (1998) also performed a comparative study between the heat integrated batch distillation and the conventional batch distillation that proved the superiority of the heat integrated scheme over its conventional counterpart in terms of energy efficiency. However, no more development has been found with regard to energy-efficient batch distillation. 2. 8 Intensified Heat Integrated Ternary Distillation Column Kiran et al. (2012) extensively investigated a novel intensified heat integrated ternary distillation column (int-HITDiC.) Their objective was to show that the int-HITDiC was superior in terms of energy consumption and economics than its general form, namely the HITDiC and the conventional standalone column. It was also investigated that the traditional HITDiC scheme shows a reasonable energy household and better economic figures than the conventional standalone column. The int-HITDiC is a hybrid scheme which gets the advantage of both the HIDiC and VRC strategies. It was found that this kind of heat integration could help to improve the process design not only in terms of thermodynamic efficiency but also in terms of capital investment. The intensified scheme can be classified into two different structure based on the number of compressors: the single compressor int-HITDiC and the double compressor int-HITDiC. From experimentation it was found that the double compressor system provided the best performance in terms of cost and energy consumption where it produced a maximum energy saving of 59.15%. Another attraction of the proposed double compressor int-HITDiC was its least payback time of excess capital which was 3.44 years. The performance of this proposed thermal integration techniques was measured using a ternary distillation system. A more general conclusion regarding energy and economic viewpoints could be found by extending its application to other example processes and checking for a consistent performance. An issue that should be mentioned regarding intensification is that although economic benefit is usually achieved the operability of the column tends to be reduced. Also, if the HIDiC is sensitive to disturbances then potentially the economic, safety and environmental performance may be unfavourably affected (Kiran et al, 2012.) 2.9 Internally Heat-Integrated Reactive Distillation Processes Internally heat-integrated distillation and reactive distillation are two promising technologies that can potentially result in considerable economical benefits. Jiao et al. (2012) conducted a study regarding internally heat-integrated reactive distillation; a technology which combines internally heat-integrated distillation and reactive distillation and is employed in order to further enhance the advantages of both technologies. The study tested three ideal quaternary systems, that reactive distillation processes with internal heat integration have been designed to use, to find which had the best potential for decreasing the total annual cost. These systems are types IP  and IIP  with stoichiometric design and also type IR which has excess design. In the case of type IP which has the reaction zone located in the centre of the reactive distillation column (RDC,) M-HIRDC will provide the highest economical benefit for the endothermic and exothermic reactions, chemical equilibrium constants and various relative volatilities. Here the reaction rate in the reactive trays in the high pressure section increases while in the reactive trays located in the pressure section the reaction rate will decrease. It is desirable to use HIRDC. The reaction zone is located at the bottom of the RDC when using type IIP  . Here the process with M-HIRDC will have better economical design than that of a conventional reaction distillation process in the case of both exothermic and endothermic reactions. The M-HIRDCs reactive trays are mostly positioned in the low-pressure section. Due to low pressure and temperature values the reaction rate is also smaller. It can be concluded that there are only minimal benefits to using HIRDC. The final system, type IR, has its reaction zone placed at the top of the RDC. This process shows the smallest total annual cost for the endothermic and exothermic reactions. The reactive trays are situated in the HP section and due to the increased temperature and pressure values the reaction rate is also increased. Thus, HIRDC is again a desirable operation. In conclusion, when the reaction zone is situated at the top of the column the lowest total annual cost will be found for the RDC. 2.10 Externally Heat-Integrated Double Distillation Column Liu et al. (2011) investigated the potential of externally heat-integrated double distillation columns (EHIDDiC.) In terms of the separation of an ideal binary mixture of hypothetical components A and B, the synthesis and design of the EHIDDiC were studied with the assumption of a constant pressure elevation between the low-pressure (LP) to the high-pressure (HP) distillation columns that are involved. It was found employing between one and three external heat exchangers results in a reasonable design option for the EHIDDiC. When a number of external heat exchangers greater than three were employed the process configuration has to be carefully determined as the increase in number of stages externally heat-integrated may not actually be beneficial to the system performance. This is due to the strong mass and heat couple between the LP and HP distillation columns that are involved and reflects the unique feature of the EHIDDiC. To reduce capital investment, the total external heat exchange areas should be installed through as small a number of heat exchangers as possible. The extreme situation would be the employment of a single external heat exchanger which would need knowledge in arranging the total heat heat transfer areas between the HP and LP distillation columns involved. These findings are of great significance both to process synthesis and design. A novel decentralised control scheme was also proposed for use for EHIDDiC operation. (Liu et al, 2011.) Huang et al. (2011) investigated three different configurations for externally heat-integrated double distillation columns performances for separating a binary mixture of ethylene and ethane. The configurations were a symmetrical EHIDDiC (S-EHIDDiC), an asymmetrical EHIDDiC (A-EHIDDiC), and a simplified asymmetrical EHIDDiC (SA-EHIDDiC), which were compared with respect to aspects related to process design and controllability. It was found that the A-EHIDDiC and SA-EHIDDiC were both superior to the S-EHIDDiC in terms of thermodynamic efficiency as well as in terms of process dynamics and controllability. Upon comparing the A -EHIDDiC and SA-EHIDDiC, the latter showed similar behaviour with the former in terms of process design and controllability. These results demonstrated that the asymmetrical configuration should generally be favoured over the symmetrical one for the development of the EHIDDiC (Huang et al, 2011.) 2.11 The structured heat integrated distillation column Krikken et als (2012) recent investigation into a structured heat integrated distillation column showed that a plate-packing configuration using structured packing gave a superior performance in comparison with the HIDIC based on the plate-fin heat exchanger. Further experimentation showed that the mass transfer and heat transfer efficiency increased significantly with increasing throughput. However, this was accompanied by an increasing pressure drop per stage. By simulating an industrial scale plate-packing unit it was found that an even better performance is possible through increasing the volumetric thermal load by further optimisation of the internals. The principle of a S-HIDiC is shown in figure 9. Here the rectifier and the stripper are alternatively stacked in a sandwich of layers which creates a high surface area for the heat and mass transfer while maintaining a high voidage. Full-size image (36 K) Figure Flow scheme of an S-HIDiC.(Krikken et al, 2012) Internals are used inside the layers to optimize the HIDIC performance. In the plate-packing HIDiC, which was developed and tested in this study, both heat and mass transfer are in balance at an acceptable pressure drop. This result of this is a column design providing substantial cost and energy savings. It could be possible to optimise the column configuration even further by decreasing the number of heat integrated stages and by increasing the volumetric thermal load but research is ongoing with regard to this. It is also important to note that the results obtained were purely based on one experience with conventional packed columns so further optimisation of the performance through adjustment of the internals is required. It was also noted that in order to achieve this development of design models would be useful (Krikken et al, 2012.) 2.12 Other Noteworthy Techniques Other techniques worth mentioning but are not explored in detail here are the inter-coupled column, concentric HIDiC, the fractionating heat-exchanger (all outlined by Jana, 2009,) control systems for heat integrated distillation systems with a multicomponent stream (Amidpour et al. 2012) and membrane distillation system using heat exchanger networks (Lu et al. 2012.) 3 Industrial Applications 3.1 Using i-HIDiC to Separate a Close-boiling Mixture It has already been proven that HIDiC can be superior in terms of energy savings when compared to other thermally coupled and conventional distillation columns. In an attempt to broaden the application of the ideal integration concept the economical and operational feasibility of the i-HIDiC scheme has been explored for the use in separating components of a close-boiling multicomponent mixture. It was found to be possible to employ two ideal HIDiCs to separate a hypothetical close boiling ternary mixture and two options of a direct and indirect sequence have been considered just as with its conventional equivalent. It has been previously found that it possible to achieve 30% to 50% energy savings for the separation of two close-boiling mixtures using a HIDiC (Iwakabe et al, 2006.) However it was then found that the ideal HIDiC system is even more thermodynamically efficient than a conventional distillation system (Huang et al, 2007.) Huang et al. (2007) found a process that was conducted with minimization of the total annual cost in mind. They analysed the closed-loop controllability for the ternary mixture separation using the i-HIDiC and the intensified i-HIDiC. Upon comparison it was shown that the intensified i-HIDiC showed worse closed loop control performance with large overshoots and a longer settling out time due to the positive feedback mechanism that is involved within the intensified structure. 3.2 Heat-integrated Extractive Distillation It is not possible to separate a binary mixture which has a very low value of relative volatility as the two components will evaporate at almost the same temperature and at a similar rate. For such cases extractive distillation can be utilised where a third components called solvent (which is a high boiling and relatively non-volatile component) is added in order to alter the relative volatility of the original feed components. It has previously been investigated as to the effectiveness and operation feasibility of several energy-integrated extractive distillation technologies including the divided-wall column, Petlyuk column and heat-integrated extractive distillation scheme (Abushwireb et al, 2007.) The work included a comparison between energy-integrated extractive distillation columns and conventional extractive distillation technique based on the recovery of aromatics from pyrolysis gasoline using a solvent called  N-methylpyrolidone. The optimum design was found through using a minimal total annual cost as the objective function. The conclusion of the study was that the designed extractive distillation schemes should meet all expectations in terms of energy consumption and purity of cuts. It was shown that the heat-integrated extractive distillation configuration is the preferred option ahead of the Petlyuk column, divided-wall column and conventional column. 3.3 Separating Close-boiling Mixtures using Heat Integrated Pressure-swing Distillation Three commonly used techniques for fractionating a binary close-boiling mixture are azeotropic distillation, extractive distillation and pressure swing distillation (PSD.) The first two techniques require a third component called a solvent that enhances the relative volatility of the components that are to be separated. This can lead to certain drawbacks such as the solvent never being completely removed thus adding impurity to the products, the cost of solvent recovery, the loss of solvent and potential environmental concerns (Treybal, 1980.) These potential issues with using a solvent have allowed the PSD approach to emerge as an attractive alternative option. An important prerequisite for the use of a PSD column is that the azeotrope separate has to be pressure sensitive. Here you have a low pressure (LP) distillation column and high pressure (HP) distillation column that are combined to avoid the azeotropic point. The inclusion of the HP and LP columns in the PSD configuration allows for the possibility of heat integration to be explored. Two appropriate types of energy integration for PSD processes were shown by K. Huang et al. (2008.) The first is the condenser/reboiler type heat integration where the condenser of the HP distillation column is integrated with the reboiler of the LP distillation process. The other option is the stripping/rectifying section type heat integration where the stripping section of the LP distillation unit is coupled with the HP distillation units rectifying section. It was found that for se parating close-boiling mixtures the best option is the latter while for other types of mixtures the reverse is actually true. However it was clear that both types of heat integrated PSD column have potential for large energy savings when separating close-boiling mixtures. Yu et al. (2012) also developed a new method for separating methyal/methanol using PSD. There it was found that the fully heat-integrated pressure swing distillation process had lower costs due its energy saving capabilities. 3.4 Heat integrated Cryogenic Distillation Cryogenic distillation columns will generally operate at extremely low temperatures. An example of this the process of separating air into its basic components where the process will run at about 100K (Mandler, JA.et al. 1989.) This temperature is low enough that oxygen and nitrogen will be in their liquid state and can consequently be separated in the column. The cryogenic separation unit has a highly costly installation arranged with the condenser if the overhead vapour is meant to covert to liquid phase as the overhead vapour is enriched with more volatile component which has a very low boiling point. The heat integration principle can be used by coupling the reboiler and condenser in the cryogenic distillation unit in order to reduce this high energy cost. The energy that is expelled in the condenser can then be utilised in the reboiler. A heat integrated cryogenic distillation column (HICDiC) that is constructed with two smaller c

Friday, October 25, 2019

Segmentation Concept Essays -- Marketing

Efficient marketing strategy is rarely aimed at a large group of customers like all women, all schoolteachers or all beer drinkers, as any of the similar large groups are rather heterogeneous and may vary by age, income, needs, habits and lifestyle (McIntosh, Matthews, Mullineux, & Medland, 2010). As it is also impossible to reach each customer requirement or expectations, some distinct groups of consumers who will respond to a certain marketing mix in the same or similar way – segments – are to be identified. Segmentation is a process and result of differentiation of the consumers’ population to certain groups by number of geographic, demographic, age, economic, social and other characteristics in respect of a particular product (Sarvary, & Elberse, 2005). Global marketing introduces a better segmentation practice than just the borders between the countries. By effective application, segmentation provides global marketers with the opportunity to benefit from global standardization (like, economies of scale and positioning consistency) and at the same time meet the expectations and demand of the target group. This approach allows assessing the markets on a global or regional scale, overcoming limitations of the political boundaries that are usually used to define the market. After identifying the market segments it is necessary to assess their attractiveness by considering segment capacity, accessibility, prospective, profitability, competitiveness, compliance to company’s corporate strategy, objectives and culture, etc. Targeting is another essential tool of effective marketing strategy as it is a choice of the segment which best fits the parameters of potential customer of the product and further orientation at this segment b... ...362/146934709X467794 Tamames, R. (2000). World Economic and Environmental Order. United Nations, UNESCO, Eolss forerunner volume. Retrieved on March 27 from http://www.eumed.net/cursecon/textos/Tamames-Env_Order.pdf Walker, C. (2010). GenWorld The New Generation of Global Youth. Retrieved from Energy BBDO on March 27. http://www.energybbdo.com/uploads/GenWorld%20Overview.pdf Westjohn, S., Singh, N., & Magnusson, P. (2012). Responsiveness to Global and Local Consumer Culture Positioning: A Personality and Collective Identity Perspective. Journal Of International Marketing, 20(1), 58-73. Retrieved on March 27. doi:10.1509/jim.10.0154 http://search.ebscohost.com/login.aspx?direct=true&db=bth&AN=72034120&site=ehost-live Yankelovich, D., & Meer, D. (2006). Rediscovering Market Segmentation. Harvard Business Review, 84(2), 122-131. SMC Learning Resources.

Wednesday, October 23, 2019

A raisin in the sun coursework Essay

In this essay I am going to analyse how Lorraine Hansberry presents the transformation of Walter in the play ‘A raisin in the sun’. The pages I’m going to concentrate on are pages 1787 and 1788. A raisin in the sun portrays a few weeks in the life of the Youngers, an African-American family living on the South Side of Chicago in the 1950s. When the play opens, the Youngers are about to receive an insurance check for $10,000. This money comes from the deceased Mr. Younger’s life insurance policy. Each of the adult members of the family has an idea as to what he or she would like to do with this money. The matriarch of the family, Mama, wants to buy a house to fulfil a dream she shared with her husband. Mama’s son, Walter Lee, would rather use the money to invest in a liquor store with his friends. He believes that the investment will solve the family’s financial problems forever. Walter’s wife, Ruth, agrees with Mama, however, and hopes that she and Walter can provide more space and opportunity for their son, Travis. Finally, Beneatha, Walter’s sister and Mama’s daughter, wants to use the money for her medical school tuition. She also wishes that her family members were not so interested in joining the white world. Beneatha instead tries to find her identity by looking back to the past and to Africa. Later on in the play, the Youngers fight over their competing dreams. Ruth finds out that she is pregnant and starts to worry about the financial problems that may happen if she keeps it. Mama puts $3,500 down payment on a house and gives $6,500 to Walter from which he has to give Beneatha some for her medical school tuition. Walter on the other hand doesn’t give Beneatha her share of her money, instead gives it to Willy his friend who runs away with it. The house is in Clybourne Park, an entirely white neighbourhood. When the Youngers’ future neighbours find out that the Youngers are moving in, they send Mr Lindner, from the Clybourne Park Improvement Association, to offer the Youngers money in return for staying away. The Youngers refuse the deal. In the meantime, Beneatha rejects her suitor, George Murchison, whom she believes to be shallow and an assimulationist. Subsequently, she receives a marriage proposal from her Nigerian boyfriend, Joseph Assegai, who wants Beneatha to get a medical degree and move to Africa with him. The Youngers eventually move out of the apartment, fulfilling the family’s long-held dream. Their future seems uncertain and slightly dangerous, but they are optimistic and determined to live a better life. They believe that they can succeed if they stick together as a family and resolve to defer their dreams no longer. Various stage directions are used to show Walter’s feelings for example, when Ruth informs Walter that Mr Lindner is here ‘a long minute passes and Walter slowly gets up’ from his room. This shows that Walter is not eager to meet Mr Lindner so he takes his time. When Walter ‘slowly and awkwardly’ walks out of his room ‘passing the back of his sleeve across his mouth from time to time’ makes him seem as if he is a small chid who is sloppy and awkward. This is how he behaves throughout the play and shows the childish side of him. When Walter ‘looks down at his boys eyes’ he realises that Travis is the 6th generation in his family to live in America and should look to set an example for future generations. While Walter talks to Mr Lindner ‘he looks around and shifts from one foot to the other’ and makes short pauses in his speech showing that he is unsure and frightened about speaking out aloud in front of his family. He tries to get the point across that they are ‘very plain people’. Walter again looks away from Mr Lindner and ‘down at his shoes’ and then back up at him. This shows that he can’t maintain eye contact with Mr Lindner. This makes Walter feel shy because he is speaking to someone who is higher classed and who he feels is superior to him. He again tries to get the point across that they are plain people by telling Mr Lindner their current situation such as how he has been ‘a chauffer’ most of his life and how Ruth is a domestic worker in people’s kitchens. All this confuses Mr Lindner as he doesn’t know what Walter is trying to get across instead he listens to him and see what he has got to say. Walter now starts to tell Mr Lindner how his father ‘almost beat a man to death once because this man called him a bad name or something’. Walter asks Mr Lindner if he knows what he is talking about, he replies ‘no, I’m afraid I don’t’ this makes Walter feel as if he is the only one that understands what it feels like so he gains confidence in himself and straightens up. Walter tries to get another point across by saying that he came from people who had a lot of pride and now they don’t have the same pride. Walter tries to make out that they are still very proud and how his sister is going to be a doctor. Walter contradicts himself as in the beginning when he was arguing with Beneatha he mentioned that being a doctor is more of a males’ role and she wouldn’t be able to become one. Walter now starts to cry while facing Mr Lindner ‘eye to eye’ this makes Walter feel bad about what he has done with the money. Walter now decided to tell Mr Lindner that they are moving into the house because his father had ‘earned it’. This shows that Walter has recognised his responsibility and best interest for his family at heart. Walter’s character has evolved from a young child into manhood making him a hero of the family. Walter now has all the confidence to look Mr Lindner ‘absolutely in the eyes’ and tell him ‘we don’t want your money’. Walter finishes with a very definite statement. Doing this makes Mr Lindner feel as he is an obstruction and so should leave. The family are all excited about the wise decision Walter has made. The audience feel that in the beginning of the play Walter is selfish and money hungry because he doesn’t listen to any member of his family and only thinks about trying to get rich quickly. In the end Walter had realised what a fool he had been after losing the money his mother had trusted him with. Now he should listen to his families needs and do what he thinks is right. By making the wise decision of moving into the house he makes the audience feel as if he has become a true man and a hero to his family. Walter is virtually a new person now which people like more than what he was before. The character of Mr. Lindner makes the theme of racial discrimination prominent in the plot as an issue that the Youngers cannot avoid. The governing body of the Youngers’ new neighbourhood, the Clybourne Park Improvement Association, sends Mr. Lindner to persuade them not to move into the all-white neighbourhood. Mr. Lindner and the people he represents can only see the colour of the Younger family’s skin, and his offer to bribe the Youngers to keep them from moving threatens to tear apart the Younger family and the values for which it stands. Ultimately, the Youngers respond to this discrimination with defiance and strength. The play powerfully demonstrates that the way to deal with discrimination is to stand up to it and reassert one’s dignity in the face of it rather than allow it to pass unchecked. In my opinion I think Walter is like any other American- African in that time. He believes that money is the only thing he needs to solve all his problems but little does he know that he needs to listen to his family and not just himself. I also think that all the male roles such as Willy and his friends are bad influences on Walter as they persuaded him to give them his money which they ran off with. However the female roles such as mama and Ruth were a good influence as they all stuck together even when Walter was against them and helped Walter to see what he is throwing away. Lorraine Hansberry is trying to say that Black people in the 1950s experienced a life of discrimination in one way or another. They got here today by having defiance and strength in themselves. Even though they were not treated as equals by some white people, however they made a stand which gave them dignity and the power to be treated as equals. Though black people try to fit into a white neighbourhood they should still remember their roots and how they got here.

Tuesday, October 22, 2019

Perception of Women in Advertising Research Paper Example

Perception of Women in Advertising Research Paper Example Perception of Women in Advertising Paper Perception of Women in Advertising Paper Advertising Print advertising often portrays females as sex objects. Women are used through sex appeal to sell products that may attract males. An issue that results in this method of advertising could result In violent sexual acts that enable violence against women. The provocative clothing that women where In print ads encourage no respect from males because the women themselves are not respecting their bodies privacy. Women seek to be treated as more than sex objects, but males view these ads and e the way females are presenting themselves through the media. Media has changed over the years and is now hooked on this idea that sex appeals to young adults. They use it in commercials, advertisements, magazines and even TV shows. Sex In advertising is pornographic because It dehumidifies and objectifies people, especially woman and because It fetishists products, Imbues them with an erotic charge which dooms us to disappointment since products never can fulfill our sexual desires or meet our emotional needs (Kilojoules 594). We go out and get push up bras because theyre sexy and will make your boobs look better, but one must think does that really make us feel better having all that padding. Maybe under a shirt it looks good but it doesnt meet our emotional needs. One may make the counter argument that advertisements arent what Is causing the sexual Identities of men and women to come closer but that popular culture such as music and movies are the culprit. How the makers of the movies and music we listen to appear has a great effect on what we find desirable. It is popular culture that has the major influence on our society, not advertisements. Axe shower gels aid is one example of how advertisers portray as a sexual object women. As one examines the ad the first thing that catches ones eye would be the girl basically naked but she has whip cream covering her chest. Then the eye travels to the guy taking a shower and using axe shower gel. One would move on to the ads slogan which states The cleaner you are, the dirtier you get. The last thing that catches the eye would notice which is under he slogan which axe states that their formula is new and improved. Advertisements are everywhere. Whether youre watching television or reading a magazine, an advertisement is sure to pop up somewhere. The ad is aiming to sell Axe shower gel for men. It Is telling men If they use their product It will make them cleaner. Therefore, making them cleaner leads to them being dirtier In the bedroom. Glenn guys the expectation that because they smell nice they will take someone home, and when they dont theres disappointment for not meeting our sexual desires. Through this advertisement, Axe is promoting idea that they can help a straight young male out his lady problems with stereotypes and body wash which makes this a false leading advertisement. In the past few years, anta-advertising activists have taken to ten streets t II really. In Washington, Tort example, a Tenements group called women Fighting Back has slapped a sticker on the Cool-ad reading, Keep your ads off my body (Clark). People are fighting against the media and saying its not okay to sexually exploit everything. Although there are some people who Just dont care about their bodies being used as advertisement. According to Clark, Advertising experts have long recognized that individual elements of ads often become more important than the placement of the product. Ads depict who uses the product, how a family looks, what is beautiful and the roles played by men and women. Thats why blacks and women get upset over certain ads, says Duke University Professor William M. Barbara (Clark). This is so true because half the time when we watch these articles e remember the sexy thing the girl did instead of the product or the guy taking his shirt off. No one is really worrying about the quality of the product Just the status it will give them. There are so many issues revolving around the media but their almost unsolvable. One needs to turn around something that is so unfortunately socially acceptable. Sex does sell and our generation is so use to it. If it didnt work the products that use it the most for instance Axe wouldnt be so successful.